Katz.TheOxides History

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Crystalline silica exists in seven different forms or polymorphs, four of which are extremely rare. The three major forms, quartz, cristobalite, and tridymite, are stable at different temperatures. Within the three major forms, there are subdivisions. Geologists distinguish, for example, between alpha and beta quartz, noting that at 573 EC, quartz changes from one form to the other. Each of these subdivisions is stable under different thermal conditions. Foundry processes, the burning of waste materials, and other manufacturing procedures can create the kinds of conditions necessary for quartz to change form. In nature, quartz in its alpha, or low, form is most common, although both lightning strikes and meteorite impacts can change alpha quartz into keatite or coesite. Alpha quartz is abundant, found on every continent in large quantities. In fact, alpha quartz is so abundant and the other polymorphs of crystalline silica are so rare, some writers use the specific term quartz in place of the more general term crystalline silica.

 Cristobalite and tridymite, the rarer forms of 

cystalline silica, may also be present in volcanic tuffs.

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